The phrase "President Buchanan" refers to James Buchanan, who was the 15th president of the United States. He served from 1857 to 1861.
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When you mention "President Buchanan," you are talking about a historical figure, so you will usually use it when discussing U.S. history, especially the events leading up to the Civil War.
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Summary:
"President Buchanan" is a noun referring to James Buchanan, the 15th president of the United States. It is used in discussions about U.S.